Ordering atomic spectra
Driven by his desire to understand the periodic system of the elements,
Rydberg set out to find order in the the enormous amount of data of atomic
spectra. Their main use had been to provide fingersprints for chemical
analysis of minerals and of stars. Guided by the prior work of Liveing and
Dewar, Rydberg could discriminate among "sharp" and "diffuse" series.
Rydberg was the first to relate the "principal" lines into a distinct
series.
In order to minimize the number of calculations, he decided to introduce
the wavenumber n, which is the reciprocal of the wavelength. The
wavenumber expresses the number of waves per centimeter. Having made this
change, he began to see patterns not previously discernable. He found that
when he plotted for a given series, the difference in wavenumber versus
the ordinal number of the term m, he obtained hyperbolic-shaped
curves that were virually identical in shape for different series and
different elements.
First he tried the formula
n = no − Co/(m+m'),
where no is the series limit when the ordinal number m
approaches infinity, and Co is a constant and m' is a constant
depending on the particular series. This formula did not work very well,
and it did not give the same Co for all series.
He was just trying the formula
n = no − No/(m+m')2,
when he saw Balmer's formula for the hydrogen spectrum
λ = hm2/(m2 − 4),
which he rewrote as
n = no − 4no/m2.
This shows that hydrogen is a special case with m'=0 and
No=4no. No is a
universal constant common to all elements. Now this constant is known as
the Rydberg constant, and m' is
known as the quantum defect. Rydberg noted that m' is approximately
the same different "diffuse" or different "sharp" series, but that diffuse
and sharp series of the same order have essentially the
same value of no.
Between the principal and the sharp series of lithium, sodium, and
potassium, there is a special relationship:
±n/No = 1/(m1+m'(p))2 -
1/(m2+m'(s))2.
That is this equation will represent either a principal series or a
diffuse series, depending on which of the m integers are assumed to be
variable, when the value of 1 is assigned to the non-variable m-number.
This is a first example of the Rydberg-Ritz
combination principle.
Rydberg presented his conclusions in a
seminar 1888.
The work was published in
the proceedings of the Royal Swedish Academy of Sciences in 1890, as
"Recherches sur la constitution des spectres d'émission des
éléments chimiques".
Fight for tenure
In 1897 K.A.V. Holmgren finally retired as professor at the age of 73. As
is the custom in Sweden, the applications were reviewed by three outside
experts: Christian Christiansen from the University of Copenhagen, Clas
Bernard Hasselberg from KTH in Stockholm, and Knut Johan
Ångström from Uppsala University. Christiansen's report came in
first, it was short, recommending Rydberg as the first choice, declaring
also P.G.D. Granqvist and C.A. Mebius competent, but excluding Victor
Bäcklund from competition, because he was a mathematician.
Hasselberg and Ångström replied only after about a year. They
both also said that Bäcklund could not be considered, and that
Rydberg, Granqvist and Mebius were qualified. But they both ranked Rydberg
last, because he had just ordered others' data, and hardly done
experiments.
Christiansen warned Rydberg, who asked international collegues for letters
of support. He received very supportive letters from Heinrich Kayser, Carl
Runge, Ostwald, Eilhard Wiedemann, Walter Nernst, and others. These
testimonials swayed the Greater Consistory of May 23rd 1900, and Rydberg's
nomination was forwarded to the goverment. But then in September,
Bäcklund was appointed!
Bäcklund was a personal friend of King Oscar II. There was reaction
against this intervention in the press. Bäcklund used his influence
to have Rydberg appointed to his previous position of extrardinary
professor. The appointment came 15 March 1901. In 1908 a law was passed to
abolish the extraordinary to ordinary professorships.
Final years
Janne Rydberg was nominated for the Nobel prize by Chalier, but it was
never awarded to him. He did not even become a member of the Royals
Swedish Academy of Sciences. In 1919, shortly before his death, he was
elected a Foreign Member of the Royal Society of London. But he had been
ill and unable to work since 1914. Janne Rydberg died on 28 December of a
brain hemorrhage.
Sources:
- P. C. Hamilton, "Janne Rydberg: a physicist in 19th-century Sweden",
Thesis Harvard University 1992.
- Ingmar Bergström and Wilhelm Forsling, "I Demokritos
fotspår: en vandring genom urämnesbegreppets historia
från antiken till Nobelprisen", p372-374 (Stockholm 1992).
- Proceedings of the Rydberg centennial conference on atomic
spectroscopy, ed. Bengt Edlén, Lund universitetets årsskrift,
Andra avdelningen 50:21 (1955).
- W. F. Meggers, "Opening address", p13-14.
- Niels Bohr, "Rydberg's discovery of the spectral laws", p15-21.
- W. Pauli, "Rydberg and the periodic system of the elements", p22-26.
- Kosmos 32 (Stockholm 1954)
- Bengt Edlén, "J. R. Rydbergs vetenskapliga gärning", p9-14.
- Arvid Leide, "Janne Rydberg och hans kamp för professuren",
p15-32.
- Svensk Uppslagsbok (Malmö 1952), s v Rydberg
- Svenska män och kvinnor (Stockholm, 1949), s v Rydberg.
- G. Borelius, "J.R. Rydberg. Några minnesord ...",
Fysisk Tidsskrift (Kobenhamn) 21, 65-70 (1923).